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21.
22.
Numerical simulation and experiments were introduced to develop AA4045/AA3003 cladding billets with different clad-ratios. The temperature fields, microstructures and mechanical properties near interface were investigated in detail. The results show that cladding billets with different clad-ratios were fabricated successfully. Si and Mn elements diffused across the bonding interface and formed diffusion layer. With the increase of clad-layer thickness, the interfacial region transforms from semisolid–solid state to liquid–solid state and the diffusion layer increased from 10 to 25 μm. The hardness at interface is higher than that of AA3003 side but lower than that of the other side. The bonding strength increased with the clad-layer thickness, attributing to solution strengthening due to elements diffusion. The cladding billets were extruded into clad pipe by indirect extrusion process after homogenization. The clad pipe remained the interfacial characteristics of as-cast cladding billet and the heredity of clad-ratio during deformation was testified. 相似文献
23.
The constrained groove pressing-cross route process was implemented on a commercially annealed AA5052 alloy at room temperature, with up to two passes (strain of ~4.64) along the rolling direction and transverse direction. The results showed the formation of an ultrafine-grained structure with an average sub-grain/cell size in the 300–500?nm range. The indentation hardness and tensile strength increased significantly, up to ~75 and 105%, respectively, and became more homogenous with a uniform and isotropic trend, as compared to the annealed alloy. According to the Hall–Petch and Taylor models used, grain refinement and increasing dislocation density were proposed as the main strengthening mechanisms. Fractographic studies revealed a ductile-fracture behaviour, with a dimpled structure proportional to the UFG structure. 相似文献
24.
针对未考虑正偏心正交车铣切削层几何形状而导致难以全面反映正交车铣切削层几何形状变化规律的问题,基于正交车铣运动规律,在不考虑动力学影响的情况下,对切削层的形成过程进行了静态分析。建立的正偏心正交车铣切削层几何形状的解析模型涉及铣刀侧刃和底刃的切入/切出角度、切削厚度和切削深度。通过试验验证了该解析模型的正确性,并分析了切削参数对铣刀切削层的影响。研究结果为正偏心正交车铣切削层几何形状的变化提供了定量的分析依据,为切削力和颤振的研究提供了理论指导。 相似文献
25.
为了解决高瓦斯矿井工作面瓦斯涌出量大、瓦斯浓度高,制约工作面安全生产的问题,以亨元煤业为背景,结合矿井开采及瓦斯地质条件,确定了本煤层顺层钻孔抽采、穿层钻孔抽采邻近层和覆岩裂隙带瓦斯、以及对上隅角布置抽采管路进行抽采的综合治理方法。试验表明,工作面开采期间瓦斯涌出正常,上隅角瓦斯浓度保持在0.56%以下,实现了工作面安全高效开采。 相似文献
26.
The formation of a monolithic part during diffusion bonding is accompanied by the diffusion of atoms across the bonding planes. At sufficient low roughness, it mainly depends on the temperature and dwell time. At the same time, the diffusion process competes against grain growth. By adjusting an appropriate level of bearing pressure, it is possible to control deformation taking into account additional parameters resulting from mechanical microstructures and the design and aspect ratio of the part. Furthermore, material properties, such as the content of alloying elements, the degree of cold work hardening and the grain size, have an impact on diffusion and deformation behavior. Also the surface condition of mating surfaces is important to diffusion kinetics and the quality of the joint. Especially passivation layers of corrosion‐resistant alloys, such as stainless steels and nickel‐based alloys, impair diffusion. In contrast to this, cold work hardening at low depth below the surface, e. g. by means of a blasting processes, may facilitate formation of a good bond and help to limit grain size. For oxide dispersion‐strengthened materials, additional impacts on diffusion bonding behavior applies. 相似文献
27.
The effects of the structure of di- and triblock copolymers of poly(L-lysine) – LYS with poly(ethylene glycol) – PEG as well as the length of nonionic fragment in the LYS-PEG macromolecule on the copolymer chains conformation in the adsorption layer formed on the colloidal silica (SiO2) surface were examined. Spectrophotometry and turbidimetry were applied for the determination of copolymer adsorbed amounts and stability coefficients of silica aqueous suspensions. The electrokinetic parameters such as solid surface charge density and zeta potential were also estimated. The adsorption of LYS-PEG was proved to be the highest at pH 10 whereas the lowest adsorption on the solid surface was found for the triblock copolymer with long fragments of LYS at the same pH value. 相似文献
28.
Ozone (O3) chemistry is thought to dominate the oxidation of indoor surfaces. We consider the hypothesis that reactions taking place within indoor boundary layers result in greater than anticipated hydroxyl radical (OH) deposition rates. We develop models that account for boundary layer mass‐transfer phenomena, O3‐terpene chemistry and OH formation, removal, and deposition; we solve these analytically and by applying numerical methods. For an O3‐limonene system, we find that OH flux to a surface with an O3 reaction probability of 10?8 is 4.3 × 10?5 molec/(cm2 s) which is about 10 times greater than predicted by a traditional boundary layer theory. At very low air exchange rates the OH surface flux can be as much as 10% of that for O3. This effect becomes less pronounced for more O3‐reactive surfaces. Turbulence intensity does not strongly influence the OH concentration gradient except for surfaces with an O3 reaction probability >10?4. Although the O3 flux dominates OH flux under most conditions, OH flux can be responsible for as much as 10% of total oxidant uptake to otherwise low‐reactivity surfaces. Further, OH chemistry differs from that for ozone; therefore, its deposition is important in understanding the chemical evolution of some indoor surfaces and surface films. 相似文献
29.
关于CaCu3Ti4O12陶瓷的高介电常数机理,目前广泛接受的是非本征的内阻挡层电容模型。该模型认为在多晶中元素变价、缺陷和非化学计量比等导致的半导化晶粒被绝缘晶界层,即内阻挡层所包围。其中内阻挡层的厚度对材料的介电性能影响较大,而扫描电子显微镜(SEM)测试表明样品晶界呈稀烂的果酱状,SEM难以测量晶界区域绝缘内阻挡层厚度。本文采用正电子湮没技术表征其厚度,通过对CaCu3Ti4O12陶瓷共掺不同浓度的Al、Nb(CaCu3Ti4-xAl0.5xNb0.5xO12,x=0.2%、0.5%、5.0%)改变其晶粒和晶界的微观结构,研究CaCu3Ti4O12陶瓷高介电常数机理。正电子湮没结果显示,掺杂样品符合多普勒展宽谱S参数的变化趋势与平均寿命的变化趋势一致。x=0.5%掺杂样品的介电常数最高,其平均寿命、S参数和湮没长寿命成分均最小,阻挡层最薄。实验结果验证了描述CaCu3Ti4O12陶瓷高介电常数机理的内阻挡层电容模型的预测。 相似文献
30.
Yaxin Chen Jiexiang Tong Jiahao Dong Jing Luo Xiaoya Liu 《Small (Weinheim an der Bergstrasse, Germany)》2019,15(13)
Fast and highly efficient enrichment and separation of glycoproteins is essential in many biological applications, but the lack of materials with high capture capacity, fast, and efficient enrichment/separation makes it a challenge. Here, a temperature‐responsive core cross‐linked star (CCS) polymer with boronate affinity is reported for fast and efficient enriching and separating of glycoproteins from biological samples. The temperature‐responsive CCS polymers containing boronic acid in its polymeric arms and poly(N‐isopropyl acrylamide) in its cross‐linked core are prepared using reversible addition‐fragmentation chain transfer polymerization via an “arm‐first” methodology. The soluble boronate polymeric arms of the CCS polymers provide a homogeneous reaction system and facilitate interactions between boronic acid and glycoproteins, which leads to a fast binding/desorption speed and high capture capacity. Maximum binding capacity of the prepared CCS polymer for horseradish peroxidase is determined to be 210 mg g?1, which can be achieved within 20 min. More interestingly, the temperature‐responsive CCS polymers exhibit rapid reversible thermal‐induced volume phase transition by increasing the temperature from 15 to 30 °C, resulting in a facile and convenient sample collection and recovery for the target glycoproteins. Finally, the temperature‐responsive CCS polymer is successfully applied to enrichment of low abundant glycoproteins. 相似文献